By William B. Tolman
The 1st to mix either the bioinorganic and the organometallic view, this instruction manual presents the entire priceless wisdom in a single handy quantity. along a glance at CO2 and N2 relief, the authors talk about O2, NO and N2O binding and relief, activation of H2 and the oxidation catalysis of O2. Edited via the hugely well known William Tolman, who has received numerous awards for his learn within the box.
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Extra resources for Activation of Small Molecules: Organometallic and Bioinorganic Perspectives
The carboxylation of phenol is carried out by a phenolcarboxylase enzyme, a new type of lyase . The isolation of the enzyme from the cytoplasmic portion of the cell allows its use in vitro. In order to extend the lifetime of the enzyme, its supported form on low melting agar can be used . 4 Carboxylation of phenolphosphate to 4-hydroxybenzoic acid. also used, with an easy separation of products from the mother liquid phase containing the enzyme and nutrients. Interestingly, the enzyme can also work in scCO2 .
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9. Therefore, multielectron reduction to any reduced form of CO2 requires a considerably lower potential than the one-electron reduction to the radical anion. 9. 24 33 34 1 Carbon Dioxide Reduction and Uses as a Chemical Feedstock Since the early work of Lehn and Ziessel  several metal complexes have been used with the aim of developing an effective photocatalyst for CO2 reduction. In general, only low light efficiencies have been reached that are often coupled with low selectivity, which leaves open the need of research for developing effective systems that may find viable applications.
Activation of Small Molecules: Organometallic and Bioinorganic Perspectives by William B. Tolman